Bøker i Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition-serien

Verbindungen'" Teil B "Metall und Legierungen"' Teil D "Chemie in Loesung'" Die vorgezogene Herausgabe dieses Bandes wird durch die Tatsache gefoerdert, dass Th0 und 2 ThOrUOrMischoxide speziell fur Hochtemperaturkernreaktoren als Brutstoffe fur die Erzeugung 233 von U von Bedeutung sind.

Starting with the binary species formed between phosphorus and hydrogen, the present volume deals with the neutral mononuclear compounds PH through PH ; PH and PH are the major initial gaseous decomposition products of PH and, thus, also 2 J intermediates in many of its gas-phase reactions.

The present volume, "Organoosmium Compounds" 8 6, systematically covers the litera ture through 1992, including many later references. 80th volumes deal with trinuclear compounds with ligands other than CO which are bonded to Os by one carbon atom ("1L ligands "), regardless of whether the ligand is additionally coordinated to Os by heteroatoms.

Volume 1 (systems with hydrogen and noble gases) of this particular supplement will be published subsequently, whereas Volume 3a (boron and nitrogen), Volume 3b (boron and nitrogen, boron and fluorine), and Volume 4 (boron compounds containing Cl, Br, I, S, Se, and Te, as well as a section containing carboranes) have already been published.

The first supplement consisting of 3 volumes covered all the literature uniformly up to the end of 1977, whereas the two volumes of the 2nd supplement have extended the literature coverage of boron compounds to 1980 and the four volumes of the 3rd supplement to 1984.

The description of uranium and its compounds, for which the Gmelin Institute has started a series of volumes supplementing the main volume of 1936, follows in its arrangement closely the order chosen for the transuranium volumes.

The extraordinary quantity of material included in the Gmelin Handbook of Inorganic Chemistry can make it extremely difficult to find a specific compound using only a general un derstanding of the basic rules for the arrangement of the subject matter (the so-called "System ofthe Last Position").

The present volume describes organoberyllium compounds containing at least one berylli um-carbon bond, except the beryllium carbides and cyanides. No doubt the main reason for the apparent ban of all experimental organoberyllium chemistry is to be found in the established, and alleged, hazardous properties of beryllium compounds.

Processes for recovering fresh water from the oceans - of which men have dreamed since antiquity - have changed markedly in the last 20 years. Production of fresh water from sea and brackish waters amounts to almost two million cubic meters per day, and this is increasing by about 25% per year.

Der vorliegende Band ist der erste Erganzungsband mit Verbindungen des Wolframs zum 1933 erschienenen Hauptband ,.Wolfram". Zuerst wird die Adsorption beschrieben, und zwar wird der Sauerstoff bei tiefen Tem peraturen wie die Edelgase und der Wasserstoff nur physisorbiert, bei hoeheren Temperaturen dagegen chemisorbiert.

Organocopper reagents have found wide use in synthetic organic chemistry during the past few decades. This last volume brings to an end the series of organocopper compounds and contains an Empirical Formula and Ligand Formula Index for about 3000 organocopper compounds and reagents described in Parts 1 to 4.

The present Supplement Volume Beryllium A 3 continues and completes the description of the physical properties of the element, begun in Supplement Volume A 2, 1991, and also treats the electrochemical behavior of the metal.

With platinum and rhodium, palladium is one of the most important members of the platinum metal group. The chemistry of the palladium-hydrogen system is so large that it merits a separate volume, so this book starts with the binary oxides and oxopalladates followed by hydroxides, hydroxo complexes and aquo complexes.

Following the indium triorganyls and their adducts with Lewis bases in Section 1, the broad field of compounds of the general type R ln- n 3 n (n = 1, 2) is treated in sections 2 to 9; Ionic species, predominantly [R lnX -n]-compounds (n = 1 to 4), close the series of trivalent n 4 organoindium compounds and are collected in Section 11.

The present volume, "Manganese" D 5, continues the description of the manganese complexes. In Chapters 22 to 29 of this volume are treated complexes with amine-N-polycarboxylic acids, hydrazinecarboxylic acids, amides, hydrazides, derivatives of hydroxylamine (e.g., hydroxamic acids), oximes and nitroso compounds, azo compounds, and triazenes.