Bøker i Springer Theses-serien

This thesis describes in-depth studies of the remarkable electronic transport within the ultrahigh conductivity delafossite metals PtCoO_2 and PdCoO_2 using the tool of focused ion beam (FIB) microstucturing. Despite being first synthesised over 50 years ago, important questions remain regarding both the origin of the unusually high conductivity of these compounds and the consequences of their unique properties for unconventional electronic transport, such as that within the ballistic regime. The thesis explores both these areas.High-energy electron irradiation is used to examine the effects of deliberately introducing point defects into PdCoO_2 and PtCoO_2, demonstrating that the extremely low resistivity of these materials stems from an extreme purity as high as 1 defect in 120,000 atoms, rather than a novel scattering suppression mechanism. In addition, studies of the electronic transport in micron-scale squares of these metals show that their broadly hexagonal Fermi surfaces lead not only to long range ballistic behaviour but novel ballistic regime phenomena which cannot be observed in materials with a higher-symmetry Fermi surface.

This work systematically investigates the use of high-quality (high-Q) resonators as coding particles of chipless cooperative radar targets to overcome clutter. Due to their high-Q, the backscattered signature can outlast clutter and permit reliable readouts in dynamic environments as well as its integration in other types of cooperative radar targets for joint identification, sensing, and ranging capabilities.This is first demonstrated with temperature and pressure sensors in the microwave frequency range, which include the characterization of a novel temperature sensor for machine tool monitoring up to 400 (deg)C, as well as inside the machine. Afterwards, the thesis proposes and demonstrates the use of metallic as well as dielectric Electromagnetic BandGap (EBG) structures to enable the realization and to enhance the capabilities at mm-Wave and THz frequencies compared to microwave frequencies with compact monolithic multi-resonator cooperative radar targets. Furthermore, this work studies the integration of resonators as coding particles inside larger retroreflective configurations such as Luneburg lenses to achieve long-range and high accuracy for localization and, at the same time, frequency coding robust against clutter for identification. Finally, the successful readout of these cooperative radar targets is demonstrated in cluttered dynamic environments, as well as with readers based on Frequency-Modulated Continuous-Wave (FMCW) radars.

This book presents innovative laser desorption ionization (LDI)-active nanophotonic structures for addressing the challenges that matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS) is currently facing and for enhancing LDI efficiency. It presents a variety of cutting-edge nanophotonic structures to satisfy the mass-analytical needs of sensitivity, reproducibility, and quantification. As opposed to the commercialized, conventional organic matrix used in MALDI-MS, these nanostructures are validated to be highly effective in detecting small metabolites and drugs, highlighting their considerable potential in the mass spectrometry field. It also systematically elucidates fundamental LDI processes in terms of the photo-thermal, electronic, and structural characteristics of nanophotonic structures, offering mechanistic knowledge of LDI-MS. Even though LDI-MS performance is heavily influenced by a number of nanostructure parameters, relatively little is known about the LDI processes associated with those characteristics. An in-depth understanding of nanostructure characteristics and LDI mechanisms thus paves the way for more effective, rational design and development of nanostructures with improved LDI capabilities. Further, with a focus on multiple cascades in nanostructure functions in response to laser pulse stimuli, this book provides detailed, step-by-step procedures to design and construct a nanophotonic, LDI-active platform, which may serve as a roadmap for graduate students in the field of mass spectrometry. Readers, including graduate students, researchers, and experts working in the related areas of mass spectrometry, nanophotonics, and material science and material engineering, will find a wealth of useful information in this book.

This book introduces readers to the preparation of two-dimensional metal sulfide/oxide for CO2 photoreduction. Based on two-dimensional metal sulfide/oxide materials, this book establishes the structure-to-property relationships of photocatalyst for CO2 photoreduction, and reveals the intrinsic mechanism of the CO2 photoreduction by virtue of the in situ characterization techniques and the density functional theory calculations. It is anticipated that this book will help to identify empirical guidelines for designing and fabricating high-performance catalysts of solar-driven CO2 reduction.

This thesis makes significant advances towards an understanding of superconductivity in the cuprate family of unconventional, high-temperature superconductors. Even though the high-temperature superconductors were discovered over 35 years ago, there is not yet a general consensus on an acceptable theory of superconductivity in these materials. One of the early proposals suggested that collective magnetic excitations of the conduction electrons could lead them to form pairs, which in turn condense to form the superconducting state at a critical temperature Tc. Quantitative calculations of Tc using experimental data were, however, not available to verify the applicability of this magnetic mechanism. In this thesis, the author constructed an angle-resolved photoemission apparatus that could provide sufficiently accurate data of the electronic excitation spectra of samples in the normal state, data which was furthermore unusually devoid of any surface contamination. The author also applied the Bethe-Salpeter method to his uncommonly pristine and precise normal state data, and was able to predict the approximate superconducting transition temperatures of different samples. This rare combination of experiment with sophisticated theoretical calculations leads to the conclusion that antiferromagnetic correlations are a viable candidate for the pairing interaction in the cuprate superconductors.

This thesis highlights research explorations in quantum contextuality with photons.Quantum contextuality is one of the most intriguing and peculiar predictions of quantum mechanics. It is also a cornerstone in modern quantum information science. It is the origin of the famous quantum nonlocality and various nonclassical paradoxes. It is also a resource for many quantum information processing tasks and even universal quantum computing. Therefore, the study of quantum contextuality not only advances the comprehension of the foundations of quantum physics, but also facilitates the practical applications of quantum information technology.In the last fifteen years, the study of quantum contextuality has developed from a purely theoretical level to a stage where direct experimental tests become amenable. However, the experimental research on contextuality at the current stage largely focuses on direct validations of some most famous predictions of contextuality, while other forms of contextuality and its practical applications in quantum information science are rarely involved. The research in this thesis is committed to bridge this gap from two directions: (1) to construct and test stronger forms of contextuality and relieve the requirements of contextuality experiments on experimental platforms, and (2) to explore the connections between contextuality and the other concepts in quantum information science and directly demonstrate the application of contextuality in broader scenarios. Specifically, the thesis have discussed the research topics about the relationship between quantum contextuality and nonlocality, the ¿all-versus-nothing¿ paradoxes from quantum contextuality, the ore- and post-selection paradoxes from quantum contextuality, and the topological protection and braiding dynamics of quantum contextuality in quasiparticle systems.

The structure of quantum theory permits interference of indistinguishable paths. At the same time, however, it also limits such interference to certain orders and any higher-order interference is prohibited. This thesis develops and studies concepts to test quantum theory with higher-order interference using many-particle correlations, the latter being generally richer and typically more subtle than single-particle correlations. It is demonstrated that quantum theory in general allows for interference up to order 2M in M-particle correlations. Depending on the mutual coherence of the particles, however, the related interference hierarchy can terminate earlier. In this thesis, we show that mutually coherent particles can exhibit interference of the highest orders allowed. We further demonstrate that interference of mutually incoherent particles truncates already at order M+1, although interference of the latter is principally more multifaceted than their coherent counterpart. We introduce two families of many-particle Sorkin parameters, whose members are expected to be all zero when quantum mechanics holds. As proof of concept, we demonstrate the disparate vanishing of such higher-order interference terms as a function of coherence in experiments with mutually coherent and incoherent sources. Finally, we investigate the influence of exotic kinked or looped quantum paths, which are permitted by Feynman's path integral approach, in such setups.

This book reports a study of a class of Dion-Jacobson-type layered perovskite oxides in which high oxide-ion conductivities in phases were discovered for the first time in the world. The oxide-ion conductors are important in various energy conversion devices and environmental protection applications such as solid-oxide fuel cells, oxygen gas sensors, oxygen separation membranes, and oxygen-based catalysts. The discoveries are based on a new screening method, called the bond valence method, combined with an original design concept. The present finding of high oxide-ion conductivity reported in the thesis suggested the potential of Dion-Jacobson phases as a platform to identify superior oxide-ion conductors.To understand what causes such high oxide-ion conductivities in these layered perovskite oxides, the author analyzed their crystal structures at high temperature and described the relationship between oxide-ion conductivities and their crystal structures. A deep understanding of the mechanisms of oxide-ion diffusivity at an atomic level in the Dion-Jacobson phases is clarified.The discovery of these materials, the new screening method, and the original design concept make possible the realization of many environment-friendly technologies. The findings in this thesis facilitate the possibilities for many novel applications that will help lead to a sustainable future.

The thesis tackles two distinct problems of great interest in gravitational mechanics ¿ one relativistic and one Newtonian. The relativistic one is concerned with the "first law of binary mechanics", a remarkably simple variational relation that plays a crucial role in the modern understanding of the gravitational two-body problem, thereby contributing to the effort to detect gravitational-wave signals from binary systems of black holes and neutron stars. The work reported in the thesis provides a mathematically elegant extension of previous results to compact objects that carry spin angular momentum and quadrupolar deformations, which more accurately represent astrophysical bodies than mere point particles. The Newtonian problem is concerned with the isochrone problem of celestial mechanics, namely the determination of the set of radial potentials whose bounded orbits have a radial period independent of the angular momentum. The thesis solves this problem completely ina geometrical way and explores its consequence on a variety of levels, in particular with a complete characterisation of isochrone orbits. The thesis is exceptional in the breadth of its scope and achievements. It is clearly and eloquently written, makes excellent use of images, provides careful explanations of the concepts and calculations, and it conveys the author¿s personality in a way that is rare in scientific writing, while never sacrificing academic rigor.

This book presents the observation and the control of spin-polarized electrons in Rashba thin films and topological insulators, including the first observations of a weak topological insulator (WTI) and a higher-order topological insulator (HOTI) in bismuth halides. It begins with a general review of electronic structures at the solid surface and mentions that an electron spin at a surface is polarized due to the Rashba effect or topological insulator states with strong spin-orbit coupling. Subsequently it describes the experimental techniques used to study these effects, that is, angle-resolved photoemission spectroscopy (ARPES). Further it moves its focus onto the experimental investigations, in which mainly two different systems-noble metal thin films with the Rashba effects and bismuth halides topological insulators-are used. The study of the first system discusses the role of wavefunctions in spin-splitting and demonstrates a scaling law for the Rashba effect in quantum well films for the first time. High-resolution spin-resolved ARPES plays a vital role in systematically trace the thickness-evolution of the effect. The study of the latter material is the first experimental demonstration of both a WTI and HOTI state in bismuth iodide and bismuth bromide, respectively. Importantly, nano-ARPES with high spatial resolution is used to confirm the topological surface states on the side surface of the crystal, which is the hallmark of WTIs.The description of the basic and recently-developed ARPES technique with spin-resolution or spatial-resolution, essential in investigating spin-polarized electrons at a crystal surface, makes the book a valuable source for researchers not only in surface physics or topological materials but also in spintronics and other condensed-matter physics.

How planets form is one of the long-standing questions in astrophysics. In particular, formation scenarios of planetesimals which are kilometer-sized bodies and a precursor of planets are still unclear and under debate although some promising mechanisms have been proposed.This book highlight disk instabilities that have the potential to explain the origin of planetesimals. Using linear analyses and numerical simulations, it addresses how a disk evolves through the development of instabilities, and also presents a new instability driven by dust coagulation. As a result, the simulation demonstrates a scenario of planetesimal formation: A successive development of multiple instabilities triggers planetesimal formation in resulting dusty rings.

This book constructs a non-Bloch band theory and studies physics described by non-Hermitian Hamiltonian in terms of the theory proposed here.In non-Hermitian crystals, the author introduces the non-Bloch band theory which produces an energy spectrum in the limit of a large system size. The energy spectrum is then calculated from a generalized Brillouin zone for a complex Bloch wave number. While a generalized Brillouin zone becomes a unit circle on a complex plane in Hermitian systems, it becomes a circle with cusps in non-Hermitian systems. Such unique features of the generalized Brillouin zone realize remarkable phenomena peculiar in non-Hermitian systems. Further the author reveals rich aspects of non-Hermitian physics in terms of the non-Bloch band theory. First, a topological invariant defined by a generalized Brillouin zone implies the appearance of topological edge states. Second, a topological semimetal phase with exceptional points appears, The topological semimetal phase is unique to non-Hermitian systems because it is caused by the deformation of the generalized Brillouin zone by changes of system parameters. Third, the author reveals a certain relationship between the non-Bloch waves and non-Hermitian topology.

This book highlights the most complete characterization of the Higgs boson properties performed to date in the "golden channel," i.e., decay into a pair of Z bosons which subsequently decay into four leptons. The data collected by the CMS experiment in the so-called Run-II data-taking period of the LHC are used to produce an extensive set of results that test in detail the predictions of the Standard Model.Given the remarkable predictive power of the SM when including the Higgs boson, possible new physics will require even more extensive studies at higher statistics. A massive upgrade of the detectors is necessary to maintain the current physics performance in the harsh environment of the High-Luminosity LHC (HL-LHC) project, expected to start by the end of 2027. The CMS Collaboration will replace the current endcap calorimeters with a High Granularity Calorimeter (HGCAL). The HGCAL will be the very first large-scale silicon-based imaging calorimeter ever employed in ahigh-energy physics experiment. This book presents the results of the analysis of the test beam data collected with the first large-scale prototype of the HGCAL. The results of this analysis are used to corroborate the final design of the HGCAL and its nominal physics performance expected for the HL-LHC operations.

This book offers a systematic study of control algorithms applied in the operation of solar membrane distillation (SMD) facilities. After a short introduction to membrane distillation systems powered by solar energy, it reports on the various stages of the development of a comprehensive operating strategy, based on modelling, control, and optimization techniques, which enables an improved operation of SMD plants helping the commercialization of the SMD technology. A special focus of the research was to maximize the distillate production of the MD modules while reducing their thermal energy consumption, being those two important weaknesses of the current technology, as well as their minimizing operating costs. The optimised operating strategies were tested in a real pilot plant located at Plataforma Solar de Almería (a dependency of the Centro de Investigaciones Energéticas, Medioambientales y Tecnológicas, CIEMAT, of Spain). All in all, this thesis offers extensive information on control and modeling algorithms, and on their practical applications in solar membrane distillation plants.

This thesis presents research on novel laboratory-scale synchrotron X-ray sources based on inverse Compton scattering and applications of their X-ray radiation using the Munich Compact Light Source (MuCLS) as an example. It provides an introduction to the theory of this laser-electron interaction, laser resonators and X-ray interactions with matter. On this basis, upgrades to the laser system including the development of a new laser optic, X-ray beam stabilisation and two techniques for fast X-ray energy switching of inverse Compton sources are presented. On the application side, the beamline, designed and developed for the inverse Compton X-ray source at the MuCLS, is described before various techniques and applications are demonstrated at this laboratory-scale synchrotron X-ray facility. Among them are K-edge subtraction imaging, X-ray phase contrast imaging and X-ray absorption spectroscopy. Additionally, a new X-ray microscopy technique, called full-field structured-illuminationsuper-resolution X-ray transmission microscopy, is presented.Apart from research conducted at the MuCLS, this thesis contains an in-depth overview on the state of the art of the various types of inverse Compton X-ray sources that have been realised so far. Accordingly, this thesis may serve as a guide and reference work for researchers working with inverse Compton X-ray sources as well as future users of such devices.

This book reports on a comprehensive study on a novel high-power converter, i.e. a Modular Multilevel Converter with Interleaved Half-bridge Submodules (ISM-MMC). It describes in depth its average model, the operating principles, as well as a new control method and a hybrid modulation strategy that help to exploit the benefits of the interleaving scheme. The new power converter is particularly advantageous for high-current applications that require superb quality of input/output waveforms. Moreover, this book reports on a systematic study of the current balancing problem between parallel-connected units that commutate in non-simultaneous fashion. This is a typical issue in interleaved converters, however here it is analyzed for the first time in relation to MMC-based structures. Two control strategies are proposed to cope with this matter. By using a sensorless regulation scheme, the number of required current transducers has been minimized, reducing complexity, cost, and footprintof the hardware, while providing converter with a fast and accurate current balancing. This book also offers a comprehensive comparison between several practical designs of ISM-MMC and classical MMC for an ultra-fast electrical vehicle charger. All in all, it provides graduate students and researchers, as well as field engineers and professionals with extensive information and essential practical details on the state-of-the-art MMC and ISM-MMC design.

This book introduces readers to the preparation of metal nanocrystals and its applications. In this book, an important point highlighted is how to design noble metal nanocrystals at the atomic scale for energy conversion and storage. It also focuses on the controllable synthesis of water splitting electrode materials including anodic oxygen evolution reaction (OER) and cathode hydrogen evolution reaction (HER) at the atomic level by defect engineering and synergistic effect. In addition, in-situ technologies and theoretical calculations are utilized to reveal the catalytic mechanisms of catalysts under realistic operating condition. The findings presented not only enrich research in the nano-field, but also support the promotion of national and international cooperation.

This book investigates the physics of the discovered Higgs boson and additional Higgs bosons in the extended Higgs models which includes higher-order quantum corrections. While the 125 GeV Higgs boson was discovered, the structure of the Higgs sector is still a mystery. Since the Higgs sector determines the concrete realization of the Higgs mechanism, the study of its nature is one of the central interests in current and future high-energy physics. The book begins with a review of the standard model and the two-Higgs doublet model, which is one of the representatives of the extended Higgs models. Subsequently, we discuss the studies of the two-Higgs doublet model at the lowest order of perturbation. Following the lowest-order analysis, we study the higher-order electroweak corrections in Higgs physics. After reviewing the renormalization procedure and the higher-order corrections in the decays of the discovered Higgs boson, we discuss the higher-order corrections in theHiggs strahlung process from an electron-positron collision, the decays of the additional charged and CP-odd Higgs bosons in the two-Higgs doublet model. From the series of these studies, it is found that the nature of the Higgs sector can be widely investigated by future collider experiments.

This book presents an analytical framework for calculating the fracture toughness of generally layered beam structures with an elastically coupled response and hygrothermal stresses. The beam under study features several peculiarities: it consists of multiple layers of dissimilar materials, features bending-extension coupling, and contains residual hygrothermal stresses. Here, a generic analytical model is proposed to compute the energy release rate and the mode mixity. Mechanics of composite materials, crack closure integral, and energetic methods are among the theoretical tools employed for developing the model.A wealth of new closed-form expressions is presented, together with their validation through finite element analyses, which enables investigating various material systems and testing configurations. Experimentalists will find directions for the design and interpretation of delamination tests on laminated composites with uncommon stacking sequences. At the same time, theoreticians can exploit the analytical solution as a benchmark test for more refined analytical and numerical models. Furthermore, the book gives novel insights into the fracture behavior of a titanium-to-CFRP adhesive joint, which is intended for application in the hybrid laminar flow control of a future aircraft. It reports on experiments and theoretical analyses that help understand the behavior of this novel joint. All in all, this book offers extensive updates on methods for fracture analysis of materials with an elastically coupled behavior and residual stresses. It addresses students, researchers, and engineers alike.

This book focuses on the development of novel functionalized organoboron compounds and those synthetic methods. High degrees of chemo-, regio-, and stereoselectivities of the borylation reactions are attained through catalyst design and optimization. Furthermore, the selectivity-determining mechanisms are analyzed with state-of-the-art DFT and other computational methods.In this book, the author synthesizes some multi-substituted alkenyl and allylic boronates via borylation reactions using a copper(I)/diboron catalyst system. Those compounds contain novel densely substituted and distorted structures, which have not been accessed by other methods. The high stereoselectivities are achieved by the optimization of the catalyst, especially the ligand. Some new ligands are also developed in this book. Furthermore, the derivatization of the borylation products is demonstrated to access the sterically demanding complex molecules. Also, the author performs computational analysis toreveal how the catalyst controls the selectivities. The deep insight into the reaction mechanism provides guides for rational catalyst design for not only copper(I) catalysis but also other transition metal catalysis. Thus, the content should be of interest to academic and industrial scientists in a wide range of areas.

This book describes the first application at CMS of deep learning algorithms trained directly on low-level, ¿raw¿ detector data, or so-called end-to-end physics reconstruction. Growing interest in searches for exotic new physics in the CMS collaboration at the Large Hadron Collider at CERN has highlighted the need for a new generation of particle reconstruction algorithms. For many exotic physics searches, sensitivity is constrained not by the ability to extract information from particle-level data but by inefficiencies in the reconstruction of the particle-level quantities themselves. The technique achieves a breakthrough in the reconstruction of highly merged photon pairs that are completely unresolved in the CMS detector. This newfound ability is used to perform the first direct search for exotic Higgs boson decays to a pair of hypothetical light scalar particles H¿aa, each subsequently decaying to a pair of highly merged photons äyy, an analysis once thought impossible to perform. The book concludes with an outlook on potential new exotic searches made accessible by this new reconstruction paradigm.