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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

Om Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).

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  • Språk:
  • Engelsk
  • ISBN:
  • 9783736970342
  • Bindende:
  • Paperback
  • Sider:
  • 138
  • Utgitt:
  • 20. juni 2019
  • Dimensjoner:
  • 210x148x8 mm.
  • Vekt:
  • 172 g.
  • BLACK NOVEMBER
  Gratis frakt
Leveringstid: 2-4 uker
Forventet levering: 28. november 2024

Beskrivelse av Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).

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